This leads to isotopic fractionation, the extent of which can be expressed by a fractionation factor, alpha (α), also known as a separation factor, or enrichment factor.
This factor is the ratio of the concentrations of the two isotopes in one compound divided by the ratio in the other compound. The fractionation factor is the factor by which the abundance ratio of two isotopes will change during a chemical reaction or a physical process.
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The precipitation of calcium carbonate from water is an example of an equilibrium fractionation process.
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